Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes

[Image: see text] The amide-directed synthesis of five-coordinate osmium alkylidene derivatives from alkynes is reported. These types of complexes, which have been elusive until now because of the tendency of osmium to give hydride alkylidyne species, are prepared by reaction of the dihydride OsH(2)...

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Detalles Bibliográficos
Autores principales: Casanova, Noelia, Esteruelas, Miguel A., Gulías, Moisés, Larramona, Carmen, Mascareñas, José L., Oñate, Enrique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4728614/
https://www.ncbi.nlm.nih.gov/pubmed/26877575
http://dx.doi.org/10.1021/acs.organomet.5b00777

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4728614/
https://www.ncbi.nlm.nih.gov/pubmed/26877575
http://dx.doi.org/10.1021/acs.organomet.5b00777

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