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Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes
[Image: see text] The amide-directed synthesis of five-coordinate osmium alkylidene derivatives from alkynes is reported. These types of complexes, which have been elusive until now because of the tendency of osmium to give hydride alkylidyne species, are prepared by reaction of the dihydride OsH(2)...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4728614/ https://www.ncbi.nlm.nih.gov/pubmed/26877575 http://dx.doi.org/10.1021/acs.organomet.5b00777 |