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Catalytic enantioselective synthesis of chiral organic compounds of ultra-high purity of >99% ee

Shortly after the discovery of Zr-catalyzed carboalumination of alkynes in 1978, we sought expansion of the scope of this reaction so as to develop its alkene version for catalytic asymmetric C–C bond formation, namely the ZACA (Zr-catalyzed asymmetric carboalumination of alkenes). However, this see...

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Detalles Bibliográficos
Autores principales: NEGISHI, Ei-ichi, XU, Shiqing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Japan Academy 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4729854/
https://www.ncbi.nlm.nih.gov/pubmed/26460317
http://dx.doi.org/10.2183/pjab.91.369