Solving the puzzling competition of the thermal C(2)–C(6) vs Myers–Saito cyclization of enyne-carbodiimides

The mechanism of the thermal cyclization of enyne-carbodiimides 7a–c has been studied computationally by applying the DFT method. The results indicate that enyne-carbodiimides preferentially follow the C(2)–C(6) (Schmittel) cyclization pathway in a concerted fashion although the Myers–Saito diradica...

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Detalles Bibliográficos
Autores principales: Rana, Anup, Cinar, Mehmet Emin, Samanta, Debabrata, Schmittel, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4734315/
https://www.ncbi.nlm.nih.gov/pubmed/26877807
http://dx.doi.org/10.3762/bjoc.12.6

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4734315/
https://www.ncbi.nlm.nih.gov/pubmed/26877807
http://dx.doi.org/10.3762/bjoc.12.6

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