Base metal-catalyzed benzylic oxidation of (aryl)(heteroaryl)methanes with molecular oxygen

The methylene group of various substituted 2- and 4-benzylpyridines, benzyldiazines and benzyl(iso)quinolines was successfully oxidized to the corresponding benzylic ketones using a copper or iron catalyst and molecular oxygen as the stoichiometric oxidant. Application of the protocol in API synthes...

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Detalles Bibliográficos
Autores principales: Sterckx, Hans, De Houwer, Johan, Mensch, Carl, Herrebout, Wouter, Tehrani, Kourosch Abbaspour, Maes, Bert U W
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4734388/
https://www.ncbi.nlm.nih.gov/pubmed/26877817
http://dx.doi.org/10.3762/bjoc.12.16

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4734388/
https://www.ncbi.nlm.nih.gov/pubmed/26877817
http://dx.doi.org/10.3762/bjoc.12.16

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