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Base metal-catalyzed benzylic oxidation of (aryl)(heteroaryl)methanes with molecular oxygen
The methylene group of various substituted 2- and 4-benzylpyridines, benzyldiazines and benzyl(iso)quinolines was successfully oxidized to the corresponding benzylic ketones using a copper or iron catalyst and molecular oxygen as the stoichiometric oxidant. Application of the protocol in API synthes...
Autores principales: | Sterckx, Hans, De Houwer, Johan, Mensch, Carl, Herrebout, Wouter, Tehrani, Kourosch Abbaspour, Maes, Bert U W |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4734388/ https://www.ncbi.nlm.nih.gov/pubmed/26877817 http://dx.doi.org/10.3762/bjoc.12.16 |
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