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Enantioselective additions of copper acetylides to cyclic iminium and oxocarbenium ions

The development of enantioselective, copper-catalyzed alkynylations of cyclic iminium and oxocarbenium ions is reviewed. The use of chiral copper-based catalysts has enabled high yields and enantioselectivites in the formation of nitrogen- and oxygen-containing heterocycles with α-stereogenic center...

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Detalles Bibliográficos
Autores principales: Liu, Jixin, Dasgupta, Srimoyee, Watson, Mary P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4734405/
https://www.ncbi.nlm.nih.gov/pubmed/26877791
http://dx.doi.org/10.3762/bjoc.11.290