Pyridylidene ligand facilitates gold-catalyzed oxidative C–H arylation of heterocycles

Triaryl-2-pyridylidene effectively facilitates the gold-catalyzed oxidative C–H arylation of heteroarenes with arylsilanes as a unique electron-donating ligand on gold. The employment of the 2-pyridylidene ligand, which is one of the strongest electron-donating N-heterocyclic carbenes, resulted in t...

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Detalles Bibliográficos
Autores principales: Hata, Kazuhiro, Ito, Hideto, Segawa, Yasutomo, Itami, Kenichiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4734412/
https://www.ncbi.nlm.nih.gov/pubmed/26877796
http://dx.doi.org/10.3762/bjoc.11.295

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4734412/
https://www.ncbi.nlm.nih.gov/pubmed/26877796
http://dx.doi.org/10.3762/bjoc.11.295

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