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Active‐Metal Template Synthesis of a Halogen‐Bonding Rotaxane for Anion Recognition

The synthesis of an all‐halogen‐bonding rotaxane for anion recognition is achieved by using active‐metal templation. A flexible bis‐iodotriazole‐containing macrocycle is exploited for the metal‐directed rotaxane synthesis. Endotopic binding of a Cu(I) template facilitates an active‐metal CuAAC iodot...

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Detalles Bibliográficos
Autores principales: Langton, Matthew J., Xiong, Yaoyao, Beer, Paul D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4736451/
https://www.ncbi.nlm.nih.gov/pubmed/26500150
http://dx.doi.org/10.1002/chem.201504236