Chain Walking of Allylrhodium Species Towards Esters During Rhodium‐Catalyzed Nucleophilic Allylations of Imines

Allylrhodium species derived from δ‐trifluoroboryl β,γ‐unsaturated esters undergo chain walking towards the ester moiety. The resulting allylrhodium species react with imines to give products containing two new stereocenters and a Z‐alkene. By using a chiral diene ligand, products can be obtained wi...

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Detalles Bibliográficos
Autores principales: Martínez, Jose I., Smith, Joshua J., Hepburn, Hamish B., Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4736453/
https://www.ncbi.nlm.nih.gov/pubmed/26756445
http://dx.doi.org/10.1002/anie.201508964

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4736453/
https://www.ncbi.nlm.nih.gov/pubmed/26756445
http://dx.doi.org/10.1002/anie.201508964

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