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Molecular features in complex environment: Cooperative team players during excited state bond cleavage

Photoinduced bond cleavage is often employed for the generation of highly reactive carbocations in solution and to study their reactivity. Diphenylmethyl derivatives are prominent precursors in polar and moderately polar solvents like acetonitrile or dichloromethane. Depending on the leaving group,...

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Detalles Bibliográficos
Autores principales: Thallmair, Sebastian, Roos, Matthias K., de Vivie-Riedle, Regina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Crystallographic Association 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4752547/
https://www.ncbi.nlm.nih.gov/pubmed/26958588
http://dx.doi.org/10.1063/1.4941600