Synthesis of 1,4‐Diketones from β‐Oxo Esters and Enol Acetates by ­Cerium‐Catalyzed Oxidative Umpo­lung Reaction

Cyclic β‐oxo esters are converted with enol acetates in a cerium‐catalyzed, oxidative Umpolung reaction to furnish 1,4‐diketones with up to 95 % yield. Atmospheric oxygen is the oxidant in this process, which can be regarded as ideal from economic and ecological points of view. Further advantages of...

Descripción completa

Detalles Bibliográficos
Autores principales: Geibel, Irina, Christoffers, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4762319/
http://dx.doi.org/10.1002/ejoc.201600057

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4762319/
http://dx.doi.org/10.1002/ejoc.201600057

Ejemplares similares