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Synthesis of 1,4‐Diketones from β‐Oxo Esters and Enol Acetates by Cerium‐Catalyzed Oxidative Umpolung Reaction
Cyclic β‐oxo esters are converted with enol acetates in a cerium‐catalyzed, oxidative Umpolung reaction to furnish 1,4‐diketones with up to 95 % yield. Atmospheric oxygen is the oxidant in this process, which can be regarded as ideal from economic and ecological points of view. Further advantages of...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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WILEY‐VCH Verlag
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4762319/ http://dx.doi.org/10.1002/ejoc.201600057 |