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A cyclo‐P(6) Ligand Complex for the Formation of Planar 2D Layers

The all‐phosphorus analogue of benzene, stabilized as middle deck in triple‐decker complexes, is a promising building block for the formation of graphene‐like sheet structures. The reaction of [(CpMo)(2)(μ,η(6):η(6)‐P(6))] (1) with CuX (X=Br, I) leads to self‐assembly into unprecedented 2D networks...

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Detalles Bibliográficos
Autores principales: Heindl, Claudia, Peresypkina, Eugenia V., Lüdeker, David, Brunklaus, Gunther, Virovets, Alexander V., Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4762322/
https://www.ncbi.nlm.nih.gov/pubmed/26711699
http://dx.doi.org/10.1002/chem.201504644