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Dithienophosphole‐Based Phosphinamides with Intriguing Self‐Assembly Behavior

A new, highly adaptable type of phosphinamide‐based hydrogen bonding is representatively demonstrated in π‐conjugated phosphole materials. The rotational flexibility of these intermolecular P=O−H−N hydrogen bonds is demonstrated by X‐ray crystallography and variable‐concentration NMR spectroscopy. I...

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Detalles Bibliográficos
Autores principales: Wang, Zisu, Gelfand, Benjamin S., Baumgartner, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770448/
https://www.ncbi.nlm.nih.gov/pubmed/26833592
http://dx.doi.org/10.1002/anie.201511171