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Dithienophosphole‐Based Phosphinamides with Intriguing Self‐Assembly Behavior
A new, highly adaptable type of phosphinamide‐based hydrogen bonding is representatively demonstrated in π‐conjugated phosphole materials. The rotational flexibility of these intermolecular P=O−H−N hydrogen bonds is demonstrated by X‐ray crystallography and variable‐concentration NMR spectroscopy. I...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770448/ https://www.ncbi.nlm.nih.gov/pubmed/26833592 http://dx.doi.org/10.1002/anie.201511171 |