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Crystal structure of a Pd(4) carbonyl tri­phenyl­phosphane cluster [Pd(4)(CO)(5)(PPh(3))(4)]·2C(4)H(8)O, comparing solvates

Attempts to synthesize Au–Pd heterometallic compounds from homonuclear palladium or gold complexes, [Pd(PtBu(2))(2)] and [Au(PPh(3))Cl] in a tetra­hydro­furan (THF) solution under a CO atmosphere resulted in a homonuclear Pd cluster, namely penta­kis­(μ-carbonyl-κ(2) C:C)tetra­kis­(tri­phenyl­phosph...

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Detalles Bibliográficos
Autores principales: Robeyns, Koen, Willocq, Christopher, Tinant, Bernard, Devillers, Michel, Hermans, Sophie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770947/
https://www.ncbi.nlm.nih.gov/pubmed/26958368
http://dx.doi.org/10.1107/S205698901502441X