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Crystal structure of (Na(0.70))(Na(0.70),Mn(0.30))(Fe(3+),Fe(2+))(2)Fe(2+)(VO(4))(3), a sodium-, iron- and manganese-based vanadate with the alluaudite-type structure
The title compound, sodium (sodium,manganese) triiron(II,III) tris[vanadate(V)], (Na(0.70))(Na(0.70),Mn(0.30))(Fe(3+),Fe(2+))(2)Fe(2+)(VO(4))(3), was prepared by solid-state reactions. It crystallizes in an alluaudite-like structure, characterized by a partial cationic disorder. In the structure, f...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770949/ https://www.ncbi.nlm.nih.gov/pubmed/26958392 http://dx.doi.org/10.1107/S2056989016000931 |