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Polyyne Rotaxanes: Stabilization by Encapsulation
[Image: see text] Active metal template Glaser coupling has been used to synthesize a series of rotaxanes consisting of a polyyne, with up to 24 contiguous sp-hybridized carbon atoms, threaded through a variety of macrocycles. Cadiot–Chodkiewicz cross-coupling affords higher yields of rotaxanes than...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2016
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4772075/ https://www.ncbi.nlm.nih.gov/pubmed/26752712 http://dx.doi.org/10.1021/jacs.5b12049 |