Polyyne Rotaxanes: Stabilization by Encapsulation

[Image: see text] Active metal template Glaser coupling has been used to synthesize a series of rotaxanes consisting of a polyyne, with up to 24 contiguous sp-hybridized carbon atoms, threaded through a variety of macrocycles. Cadiot–Chodkiewicz cross-coupling affords higher yields of rotaxanes than...

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Detalles Bibliográficos
Autores principales: Movsisyan, Levon D., Franz, Michael, Hampel, Frank, Thompson, Amber L., Tykwinski, Rik R., Anderson, Harry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4772075/
https://www.ncbi.nlm.nih.gov/pubmed/26752712
http://dx.doi.org/10.1021/jacs.5b12049

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