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Synthesis and Photophysical Study of a [NiFe] Hydrogenase Biomimetic Compound Covalently Linked to a Re-diimine Photosensitizer

[Image: see text] The synthesis, photophysics, and photochemistry of a linked dyad ([Re]-[NiFe(2)]) containing an analogue ([NiFe(2)]) of the active site of [NiFe] hydrogenase, covalently bound to a Re-diimine photosensitizer ([Re]), are described. Following excitation, the mechanisms of electron tr...

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Detalles Bibliográficos
Autores principales: Summers, Peter A., Calladine, James A., Ghiotto, Fabio, Dawson, Joe, Sun, Xue-Z., Hamilton, Michelle L., Towrie, Michael, Davies, E. Stephen, McMaster, Jonathan, George, Michael W., Schröder, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4774970/
https://www.ncbi.nlm.nih.gov/pubmed/26605700
http://dx.doi.org/10.1021/acs.inorgchem.5b01744