Regioselective palladium-catalyzed ring-opening reactions of C1-substituted oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylates

Palladium-catalyzed ring-opening reactions of C1 substituted 7-oxanorbornadiene derivatives with aryl iodides were investigated. The optimal conditions for this reaction were found to be PdCl(2)(PPh(3))(2), ZnCl(2), Et(3)N and Zn in THF. Both steric and electronic factors played a role in the outcom...

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Detalles Bibliográficos
Autores principales: Edmunds, Michael, Raheem, Mohammed Abdul, Boutin, Rebecca, Tait, Katrina, Tam, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778517/
https://www.ncbi.nlm.nih.gov/pubmed/26977182
http://dx.doi.org/10.3762/bjoc.12.25

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778517/
https://www.ncbi.nlm.nih.gov/pubmed/26977182
http://dx.doi.org/10.3762/bjoc.12.25

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