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Tandem processes promoted by a hydrogen shift in 6-arylfulvenes bearing acetalic units at ortho position: a combined experimental and computational study

6-Phenylfulvenes bearing (1,3-dioxolan or dioxan)-2-yl substituents at ortho position convert into mixtures of 4- and 9-(hydroxy)alkoxy-substituted benz[f]indenes as result of cascade processes initiated by a thermally activated hydrogen shift. Structurally related fulvenes with non-cyclic acetalic...

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Detalles Bibliográficos
Autores principales: Alajarin, Mateo, Marin-Luna, Marta, Sanchez-Andrada, Pilar, Vidal, Angel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778534/
https://www.ncbi.nlm.nih.gov/pubmed/26977185
http://dx.doi.org/10.3762/bjoc.12.28