Highly Unsaturated Platinum and Palladium Carbenes PtC(3) and PdC(3) Isolated and Characterized in the Gas Phase

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Carbenes of platinum and palladium, PtC(3) and PdC(3), were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and ab initio calculations confirm that both...

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Detalles Bibliográficos
Autores principales: Bittner, Dror M., Zaleski, Daniel P., Tew, David P., Walker, Nicholas R., Legon, Anthony C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797365/
https://www.ncbi.nlm.nih.gov/pubmed/26879473
http://dx.doi.org/10.1002/anie.201511646

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797365/
https://www.ncbi.nlm.nih.gov/pubmed/26879473
http://dx.doi.org/10.1002/anie.201511646

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