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Synthesis and Dynamics of Nanosized Phenylene–Ethynylene–Butadiynylene Rotaxanes and the Role of Shape Persistence
Phenylacetylene‐based [2]rotaxanes were synthesized by a covalent‐template approach by aminolysis of the corresponding prerotaxanes. The wheel and the bulky stoppers are made of phenylene–ethynylene–butadiynylene macrocycles of the same size. The stoppers are large enough to enable the synthesis and...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797704/ https://www.ncbi.nlm.nih.gov/pubmed/26836984 http://dx.doi.org/10.1002/anie.201509702 |