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Synthesis and Dynamics of Nanosized Phenylene–Ethynylene–Butadiynylene Rotaxanes and the Role of Shape Persistence

Phenylacetylene‐based [2]rotaxanes were synthesized by a covalent‐template approach by aminolysis of the corresponding prerotaxanes. The wheel and the bulky stoppers are made of phenylene–ethynylene–butadiynylene macrocycles of the same size. The stoppers are large enough to enable the synthesis and...

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Detalles Bibliográficos
Autores principales:	Schweez, Christopher, Shushkov, Philip, Grimme, Stefan, Höger, Sigurd
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797704/ https://www.ncbi.nlm.nih.gov/pubmed/26836984 http://dx.doi.org/10.1002/anie.201509702

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