Investigating vibrational relaxation in cyanide-bridged transition metal mixed-valence complexes using two-dimensional infrared and infrared pump-probe spectroscopies

Using polarization-selective two-dimensional infrared (2D IR) and infrared pump-probe spectroscopies, we study vibrational relaxation of the four cyanide stretching (ν(CN)) vibrations found in [(NH(3))(5)Ru(III)NCFe(II)(CN)(5)](−) (FeRu) dissolved in D(2)O or formamide and [(NC)(5)Fe(II)CNPt(IV)(NH(...

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Detalles Bibliográficos
Autores principales: Slenkamp, Karla M., Lynch, Michael S., Brookes, Jennifer F., Bannan, Caitlin C., Daifuku, Stephanie L., Khalil, Munira
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Crystallographic Association 2016
Materias:
SPECIAL TOPIC: SELECTED PAPERS FROM THE 3RD INTERNATIONAL CONFERENCE ON ULTRAFAST STRUCTURAL DYNAMICS
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4798997/
https://www.ncbi.nlm.nih.gov/pubmed/27158634
http://dx.doi.org/10.1063/1.4943766

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4798997/
https://www.ncbi.nlm.nih.gov/pubmed/27158634
http://dx.doi.org/10.1063/1.4943766

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