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Investigating vibrational relaxation in cyanide-bridged transition metal mixed-valence complexes using two-dimensional infrared and infrared pump-probe spectroscopies
Using polarization-selective two-dimensional infrared (2D IR) and infrared pump-probe spectroscopies, we study vibrational relaxation of the four cyanide stretching (ν(CN)) vibrations found in [(NH(3))(5)Ru(III)NCFe(II)(CN)(5)](−) (FeRu) dissolved in D(2)O or formamide and [(NC)(5)Fe(II)CNPt(IV)(NH(...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Crystallographic Association
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4798997/ https://www.ncbi.nlm.nih.gov/pubmed/27158634 http://dx.doi.org/10.1063/1.4943766 |