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A Unified Treatment of the Relationship Between Ligand Substituents and Spin State in a Family of Iron(II) Complexes
The influence of ligands on the spin state of a metal ion is of central importance for bioinorganic chemistry, and the production of base‐metal catalysts for synthesis applications. Complexes derived from [Fe(bpp)(2)](2+) (bpp=2,6‐di{pyrazol‐1‐yl}pyridine) can be high‐spin, low‐spin, or spin‐crossov...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4804750/ https://www.ncbi.nlm.nih.gov/pubmed/26929084 http://dx.doi.org/10.1002/anie.201600165 |