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A Unified Treatment of the Relationship Between Ligand Substituents and Spin State in a Family of Iron(II) Complexes

The influence of ligands on the spin state of a metal ion is of central importance for bioinorganic chemistry, and the production of base‐metal catalysts for synthesis applications. Complexes derived from [Fe(bpp)(2)](2+) (bpp=2,6‐di{pyrazol‐1‐yl}pyridine) can be high‐spin, low‐spin, or spin‐crossov...

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Detalles Bibliográficos
Autores principales: Kershaw Cook, Laurence J., Kulmaczewski, Rafal, Mohammed, Rufeida, Dudley, Stephen, Barrett, Simon A., Little, Marc A., Deeth, Robert J., Halcrow, Malcolm A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4804750/
https://www.ncbi.nlm.nih.gov/pubmed/26929084
http://dx.doi.org/10.1002/anie.201600165