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Diastereomeric resolution directed towards chirality determination focussing on gas-phase energetics of coordinated sodium dissociation

Defining chiral centres is addressed by introducing a pair of chiral auxiliary groups. Ions of diastereomeric pairs of molecules could be distinguished utilising energy-resolved mass spectrometry, and the applicability of the method to a series of compounds carrying amine, carboxylic acid, alcohol,...

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Detalles Bibliográficos
Autores principales: Kanie, Osamu, Shioiri, Yuki, Ogata, Koji, Uchida, Waka, Daikoku, Shusaku, Suzuki, Katsuhiko, Nakamura, Shinichiro, Ito, Yukishige
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4819175/
https://www.ncbi.nlm.nih.gov/pubmed/27040078
http://dx.doi.org/10.1038/srep24005