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Diastereomeric resolution directed towards chirality determination focussing on gas-phase energetics of coordinated sodium dissociation
Defining chiral centres is addressed by introducing a pair of chiral auxiliary groups. Ions of diastereomeric pairs of molecules could be distinguished utilising energy-resolved mass spectrometry, and the applicability of the method to a series of compounds carrying amine, carboxylic acid, alcohol,...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4819175/ https://www.ncbi.nlm.nih.gov/pubmed/27040078 http://dx.doi.org/10.1038/srep24005 |