Spectroscopic Evidence for Clusters of Like‐Charged Ions in Ionic Liquids Stabilized by Cooperative Hydrogen Bonding

Direct spectroscopic evidence for hydrogen‐bonded clusters of like‐charged ions is reported for ionic liquids. The measured infrared O−H vibrational bands of the hydroxyethyl groups in the cations can be assigned to the dispersion‐corrected DFT calculated frequencies of linear and cyclic clusters. C...

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Detalles Bibliográficos
Autores principales: Knorr, Anne, Stange, Peter, Fumino, Koichi, Weinhold, Frank, Ludwig, Ralf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4819523/
https://www.ncbi.nlm.nih.gov/pubmed/26670942
http://dx.doi.org/10.1002/cphc.201501134

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4819523/
https://www.ncbi.nlm.nih.gov/pubmed/26670942
http://dx.doi.org/10.1002/cphc.201501134

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