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Tuning the Ground State Symmetry of Acetylenyl Radicals
[Image: see text] The lowest excited state of the acetylenyl radical, HCC, is a (2)Π state, only 0.46 eV above the ground state, (2)Σ(+). The promotion of an electron from a π bond pair to a singly occupied σ hybrid orbital is all that is involved, and so we set out to tune those orbital energies, a...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4827494/ https://www.ncbi.nlm.nih.gov/pubmed/27162981 http://dx.doi.org/10.1021/acscentsci.5b00187 |