Cooperativity between Al Sites Promotes Hydrogen Transfer and Carbon–Carbon Bond Formation upon Dimethyl Ether Activation on Alumina

[Image: see text] The methanol-to-olefin (MTO) process allows the conversion of methanol/dimethyl ether into olefins on acidic zeolites via the so-called hydrocarbon pool mechanism. However, the site and mechanism of formation of the first carbon–carbon bond are still a matter of debate. Here, we sh...

Descripción completa

Detalles Bibliográficos
Autores principales: Comas-Vives, Aleix, Valla, Maxence, Copéret, Christophe, Sautet, Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4827526/
https://www.ncbi.nlm.nih.gov/pubmed/27162986
http://dx.doi.org/10.1021/acscentsci.5b00226

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4827526/
https://www.ncbi.nlm.nih.gov/pubmed/27162986
http://dx.doi.org/10.1021/acscentsci.5b00226

Ejemplares similares