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High-Potential Electrocatalytic O(2) Reduction with Nitroxyl/NO(x) Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis

[Image: see text] Efficient reduction of O(2) to water is a central challenge in energy conversion and many aerobic oxidation reactions. Here, we show that the electrochemical oxygen reduction reaction (ORR) can be achieved at high potentials by using soluble organic nitroxyl and nitrogen oxide (NO(...

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Detalles Bibliográficos
Autores principales: Gerken, James B., Stahl, Shannon S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4827547/
https://www.ncbi.nlm.nih.gov/pubmed/27162977
http://dx.doi.org/10.1021/acscentsci.5b00163