Palladium(II)‐Catalyzed Synthesis of Sulfinates from Boronic Acids and DABSO: A Redox‐Neutral, Phosphine‐Free Transformation

A redox‐neutral palladium(II)‐catalyzed conversion of aryl, heteroaryl, and alkenyl boronic acids into sulfinate intermediates, and onwards to sulfones and sulfonamides, has been realized. A simple Pd(OAc)(2) catalyst, in combination with the sulfur dioxide surrogate 1,4‐diazabicyclo[2.2.2]octane bi...

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Detalles Bibliográficos
Autores principales: Deeming, Alex S., Russell, Claire J., Willis, Michael C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832823/
https://www.ncbi.nlm.nih.gov/pubmed/26596861
http://dx.doi.org/10.1002/anie.201508370

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832823/
https://www.ncbi.nlm.nih.gov/pubmed/26596861
http://dx.doi.org/10.1002/anie.201508370

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