Divergent C—H Insertion–Cyclization Cascades of N‐Allyl Ynamides

Gold carbene reactivity patterns were accessed by ynamide insertion into a C(sp(3))—H bond. A substantial increase in molecular complexity occurred through the cascade polycyclization of N‐allyl ynamides to form fused nitrogen‐heterocycle scaffolds. Exquisite selectivity was observed despite several...

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Detalles Bibliográficos
Autores principales: Adcock, Holly V., Chatzopoulou, Elli, Davies, Paul W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832826/
https://www.ncbi.nlm.nih.gov/pubmed/26515958
http://dx.doi.org/10.1002/anie.201507167

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832826/
https://www.ncbi.nlm.nih.gov/pubmed/26515958
http://dx.doi.org/10.1002/anie.201507167

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