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Divergent C—H Insertion–Cyclization Cascades of N‐Allyl Ynamides
Gold carbene reactivity patterns were accessed by ynamide insertion into a C(sp(3))—H bond. A substantial increase in molecular complexity occurred through the cascade polycyclization of N‐allyl ynamides to form fused nitrogen‐heterocycle scaffolds. Exquisite selectivity was observed despite several...
Autores principales: | Adcock, Holly V., Chatzopoulou, Elli, Davies, Paul W. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY‐VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832826/ https://www.ncbi.nlm.nih.gov/pubmed/26515958 http://dx.doi.org/10.1002/anie.201507167 |
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