Azaphilic versus Carbophilic Coupling at C=N Bonds: Key Steps in Titanium‐Assisted Multicomponent Reactions

Consecutive C‐ and N‐arylation of N‐heterocyclic nitriles is mediated by titanium(IV) alkoxides. The carbo‐ and azaphilic arylation step may be separated by choosing the order in which the two equivalents of aryl transfer reagent are added. In the course of this transformation, the ancillary N‐heter...

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Detalles Bibliográficos
Autores principales: Roth, Torsten, Wadepohl, Hubert, Clot, Eric, Gade, Lutz H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832833/
https://www.ncbi.nlm.nih.gov/pubmed/26542982
http://dx.doi.org/10.1002/chem.201503732

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832833/
https://www.ncbi.nlm.nih.gov/pubmed/26542982
http://dx.doi.org/10.1002/chem.201503732

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