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Easy To Synthesize, Robust Organo‐osmium Asymmetric Transfer Hydrogenation Catalysts

Asymmetric transfer hydrogenation (ATH) is an important process in organic synthesis for which the Noyori‐type Ru(II) catalysts [(arene)Ru(Tsdiamine)] are now well established and widely used. We now demonstrate for the first time the catalytic activity of the osmium analogues. X‐ray crystal structu...

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Detalles Bibliográficos
Autores principales: Coverdale, James P. C., Sanchez‐Cano, Carlos, Clarkson, Guy J., Soni, Rina, Wills, Martin, Sadler, Peter J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832837/
https://www.ncbi.nlm.nih.gov/pubmed/25853228
http://dx.doi.org/10.1002/chem.201500534