Gd(3)TCAS(2): An Aquated Gd(3+)-Thiacalix[4]arene Sandwich Cluster with Extremely Slow Ligand Substitution Kinetics

[Image: see text] In aqueous solution, Gd(3+) and thiacalix[4]arene-p-tetrasulfonate (TCAS) form the complex [Gd(3)TCAS(2)](7–), in which a trinuclear Gd(3+) core is sandwiched by two TCAS ligands. Acid-catalyzed dissociation reactions, as well as transmetalation and ligand exchange with physiologic...

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Detalles Bibliográficos
Autores principales: Iki, Nobuhiko, Boros, Eszter, Nakamura, Mami, Baba, Ryo, Caravan, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4837960/
https://www.ncbi.nlm.nih.gov/pubmed/27018719
http://dx.doi.org/10.1021/acs.inorgchem.6b00241

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4837960/
https://www.ncbi.nlm.nih.gov/pubmed/27018719
http://dx.doi.org/10.1021/acs.inorgchem.6b00241

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