Ambient‐Temperature Synthesis of 2‐Phosphathioethynolate, PCS(–), and the Ligand Properties of ECX(–) (E = N, P; X = O, S)

A synthesis of the 2‐phosphathioethynolate anion, PCS(–), under ambient conditions is reported. The coordination chemistry of PCO(–), PCS(–) and their nitrogen‐containing congeners is also explored. Photolysis of a solution of W(CO)(6) in the presence of PCO(–) [or a simple ligand displacement react...

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Detalles Bibliográficos
Autores principales: Jupp, Andrew R., Geeson, Michael B., McGrady, John E., Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4845559/
https://www.ncbi.nlm.nih.gov/pubmed/27134553
http://dx.doi.org/10.1002/ejic.201501075

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4845559/
https://www.ncbi.nlm.nih.gov/pubmed/27134553
http://dx.doi.org/10.1002/ejic.201501075

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