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Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes
An efficient and general copper(i)-catalyzed silylation of p-quinone-methides is described. Non-symmetric dibenzylic silanes are obtained in high yields under mild reaction conditions. These compounds can be used as bench-stable benzylic carbanion precursors.
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4847169/ https://www.ncbi.nlm.nih.gov/pubmed/26490453 http://dx.doi.org/10.1039/c5cc06653k |