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Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

An efficient and general copper(i)-catalyzed silylation of p-quinone-methides is described. Non-symmetric dibenzylic silanes are obtained in high yields under mild reaction conditions. These compounds can be used as bench-stable benzylic carbanion precursors.

Detalles Bibliográficos
Autores principales:	López, Aurora, Parra, Alejandro, Jarava-Barrera, Carlos, Tortosa, Mariola
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4847169/ https://www.ncbi.nlm.nih.gov/pubmed/26490453 http://dx.doi.org/10.1039/c5cc06653k

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