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Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis

[Image: see text] Single-electron transmetalation via photoredox/nickel dual catalysis provides the opportunity for the construction of C(sp(3))–C(sp(2)) bonds through the transfer of alkyl radicals under very mild reaction conditions. A general procedure for the cross-coupling of primary and second...

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Detalles Bibliográficos
Autores principales: Patel, Niki R., Kelly, Christopher B., Jouffroy, Matthieu, Molander, Gary A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4854195/
https://www.ncbi.nlm.nih.gov/pubmed/26828317
http://dx.doi.org/10.1021/acs.orglett.6b00024