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Peculiar orientational disorder in 4-bromo-4′-nitrobiphenyl (BNBP) and 4-bromo-4′-cyanobiphenyl (BCNBP) leading to bipolar crystals

180° orientational disorder of molecular building blocks can lead to a peculiar spatial distribution of polar properties in molecular crystals. Here we present two examples [4-bromo-4′-nitrobiphenyl (BNBP) and 4-bromo-4′-cyanobiphenyl (BCNBP)] which develop into a bipolar final growth state. This me...

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Detalles Bibliográficos
Autores principales: Burgener, Matthias, Aboulfadl, Hanane, Labat, Gaël Charles, Bonin, Michel, Sommer, Martin, Sankolli, Ravish, Wübbenhorst, Michael, Hulliger, Jürg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4856144/
https://www.ncbi.nlm.nih.gov/pubmed/27158508
http://dx.doi.org/10.1107/S2052252516006709