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Ultrafast electronic and vibrational dynamics in brominated aluminum corroles: Energy relaxation and triplet formation
We combined femtosecond (fs) VIS pump–IR probe spectroscopy with fs VIS pump–supercontinuum probe spectroscopy to characterize the photoreaction of the hexacoordinated Al(tpfc-Br(8))(py)(2) in a comprehensive way. Upon fs excitation at ∼400 nm in the Soret band, the excitation energy relaxes with a...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Crystallographic Association
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4866960/ https://www.ncbi.nlm.nih.gov/pubmed/27226980 http://dx.doi.org/10.1063/1.4949363 |