Synthesis and reactivity of BINEPINE-based chiral Fe(II) PNP pincer complexes

ABSTRACT: A new asymmetric chiral PNP ligand based on the 2,6-diaminopyridine scaffold featuring a R-BINEPINE moiety was prepared. Treatment of anhydrous FeX(2) (X = Cl, Br) with 1 equiv of PNP-iPr,BIN at room temperature afforded the coordinatively unsaturated paramagnetic complexes [Fe(PNP-iPr,BIN...

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Detalles Bibliográficos
Autores principales: Schröder-Holzhacker, Christian, Gorgas, Nikolaus, Stöger, Berthold, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2016
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4869728/
https://www.ncbi.nlm.nih.gov/pubmed/27340297
http://dx.doi.org/10.1007/s00706-016-1706-x

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4869728/
https://www.ncbi.nlm.nih.gov/pubmed/27340297
http://dx.doi.org/10.1007/s00706-016-1706-x

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