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Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums

Polymetalated aromatic compounds are particularly challenging synthetic goals because of the limited thermodynamic stability of polyanionic species arising from strong electrostatic repulsion between adjacent carbanionic sites. Here we describe a facile synthesis of two polyaurated complexes includi...

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Detalles Bibliográficos
Autores principales: Yuan, Jun, Sun, Tingting, He, Xin, An, Ke, Zhu, Jun, Zhao, Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4873667/
https://www.ncbi.nlm.nih.gov/pubmed/27186982
http://dx.doi.org/10.1038/ncomms11489