The Cycloaddition of the Benzimidazolium Ylides with Alkynes: New Mechanistic Insights

New insights concerning the reaction mechanism in the cycloaddition reaction of benzimidazolium ylides to activated alkynes are presented. The proposed pathway leading both to 2-(1H-pyrrol-1-yl)anilines and to pyrrolo[1,2-a]quinoxalin-4(5H)-ones involves an opening of the imidazole ring from the cyc...

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Detalles Bibliográficos
Autores principales: Moldoveanu, Costel, Zbancioc, Gheorghita, Mantu, Dorina, Maftei, Dan, Mangalagiu, Ionel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2016
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4880325/
https://www.ncbi.nlm.nih.gov/pubmed/27224656
http://dx.doi.org/10.1371/journal.pone.0156129

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4880325/
https://www.ncbi.nlm.nih.gov/pubmed/27224656
http://dx.doi.org/10.1371/journal.pone.0156129

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