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Distinct properties of semiquinone species detected at the ubiquinol oxidation Q(o) site of cytochrome bc(1) and their mechanistic implications
The two-electron ubiquinol oxidation or ubiquinone reduction typically involves semiquinone (SQ) intermediates. Natural engineering of ubiquinone binding sites of bioenergetic enzymes secures that SQ is sufficiently stabilized, so that it does not leave the site to membranous environment before full...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4892266/ https://www.ncbi.nlm.nih.gov/pubmed/27194483 http://dx.doi.org/10.1098/rsif.2016.0133 |